Acidic enol electrooxidation-coupled hydrogen production with ampere-level current density

Zheng-Jie Chen, Jiuyi Dong, Jiajing Wu, Qiting Shao, Na Luo, Minwei Xu, Yuanmiao Sun, Yongbing Tang, Jing Peng () and Hui-Ming Cheng ()
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Zheng-Jie Chen: Chinese Academy of Sciences
Jiuyi Dong: Chinese Academy of Sciences
Jiajing Wu: Shenzhen Institute of Information Technology
Qiting Shao: Chinese Academy of Sciences
Na Luo: Chinese Academy of Sciences
Minwei Xu: Chinese Academy of Sciences
Yuanmiao Sun: Chinese Academy of Sciences
Yongbing Tang: Chinese Academy of Sciences
Jing Peng: Chinese Academy of Sciences
Hui-Ming Cheng: Chinese Academy of Sciences

Nature Communications, 2023, vol. 14, issue 1, 1-9

Abstract: Abstract Hydrogen production coupled with biomass upgrading is vital for future sustainable energy developments. However, most biomass electrooxidation reactions suffer from high working voltage and low current density, which substantially hinder large-scale industrial applications. Herein, we report an acidic hydrogen production system that combined anodic ascorbic acid electrooxidation with cathodic hydrogen evolution. Unlike C-H and O-H bonds cleavage with slow kinetics in conventional organic oxidation, the highly active enol structure in ascorbic acid allows for an ultralow overpotential of only 12 mV@10 mA/cm2 using Fe single-atom catalysts, and reaches 1 A/cm2 at only 0.75 V (versus reversible hydrogen electrode) with approximately 100% Faraday efficiency for hydrogen production. Furthermore, the fabricated two-electrode membrane-free electrolyser delivers an industrial current density of 2 A/cm2@1.1 V at 60 °C (2.63 kWh/Nm3 H2), which requires half of the electricity consumption in conventional water electrolysis (~5 kWh/Nm3 H2). This work provides a new avenue for achieving industrial-scale hydrogen production from biomass.

Date: 2023
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DOI: 10.1038/s41467-023-39848-w

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