Improving the photovoltage of Cu2O photocathodes with dual buffer layers

Jinshui Cheng, Linxiao Wu and Jingshan Luo ()
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Jinshui Cheng: Renewable Energy Conversion and Storage Center, Nankai University
Linxiao Wu: Renewable Energy Conversion and Storage Center, Nankai University
Jingshan Luo: Renewable Energy Conversion and Storage Center, Nankai University

Nature Communications, 2023, vol. 14, issue 1, 1-10

Abstract: Abstract Cuprous oxide (Cu2O) is a promising oxide material for photoelectrochemical water splitting (PEC), and increasing its photovoltage is the key to creating efficient overall PEC water-splitting devices. Previous reports are mostly focused on optimizing the energy band alignment between Cu2O and the n-type buffer layer to improve the photovoltage of Cu2O photocathodes. However, the band alignment between the n-type buffer layer and the protective layer is often ignored. In this work, Cu2O photocathodes with a single buffer layer (Ga2O3) and dual buffer layers (Ga2O3/ZnGeOx) are fabricated, and their PEC performances are compared. Results show that after inserting the second buffer layer (ZnGeOx), the onset potential of the Cu2O photocathode increases by 0.16 V. Operando electrochemical impedance spectroscopy measurements and analysis of the energy-level diagrams of each layer show that an energy level gradient between Ga2O3 and TiO2 is created when ZnGeOx is introduced, which eliminates the potential barrier at the interface of Ga2O3/TiO2 and improves the photovoltage of the Cu2O photocathode. Our work provides an effective approach to improve the photovoltage of photoelectrodes for solar water splitting by introducing dual buffer layers.

Date: 2023
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DOI: 10.1038/s41467-023-42799-x

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