A general large-scale synthesis approach for crystalline porous materials

Xiongli Liu, An Wang, Chunping Wang, Jinli Li, Zhiyuan Zhang, Abdullah M. Al-Enizi, Ayman Nafady, Feng Shui, Zifeng You, Baiyan Li (), Yangbing Wen () and Shengqian Ma ()
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Xiongli Liu: Nankai University
An Wang: Tianjin University of Science and Technology
Chunping Wang: Tianjin University of Science and Technology
Jinli Li: Nankai University
Zhiyuan Zhang: Nankai University
Abdullah M. Al-Enizi: King Saud University
Ayman Nafady: King Saud University
Feng Shui: Nankai University
Zifeng You: Nankai University
Baiyan Li: Nankai University
Yangbing Wen: Tianjin University of Science and Technology
Shengqian Ma: University of North Texas 1508 W Mulberry St

Nature Communications, 2023, vol. 14, issue 1, 1-10

Abstract: Abstract Crystalline porous materials such as covalent organic frameworks (COFs), metal-organic frameworks (MOFs) and porous organic cages (POCs) have been widely applied in various fields with outstanding performances. However, the lack of general and effective methodology for large-scale production limits their further industrial applications. In this work, we developed a general approach comprising high pressure homogenization (HPH), which can realize large-scale synthesis of crystalline porous materials including COFs, MOFs, and POCs under benign conditions. This universal strategy, as illustrated in the proof of principle studies, has prepared 4 COFs, 4 MOFs, and 2 POCs. It can circumvent some drawbacks of existing approaches including low yield, high energy consumption, low efficiency, weak mass/thermal transfer, tedious procedures, poor reproducibility, and high cost. On the basis of this approach, an industrial homogenizer can produce 0.96 ~ 580.48 ton of high-performance COFs, MOFs, and POCs per day, which is unachievable via other methods.

Date: 2023
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DOI: 10.1038/s41467-023-42833-y

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