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Tough soldering for stretchable electronics by small-molecule modulated interfacial assemblies

Liqing Ai, Weikang Lin, Chunyan Cao, Pengyu Li, Xuejiao Wang, Dong Lv, Xin Li, Zhengbao Yang () and Xi Yao ()
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Liqing Ai: City University of Hong Kong
Weikang Lin: Hong Kong University of Science and Technology
Chunyan Cao: City University of Hong Kong
Pengyu Li: Hong Kong University of Science and Technology
Xuejiao Wang: City University of Hong Kong
Dong Lv: City University of Hong Kong
Xin Li: City University of Hong Kong
Zhengbao Yang: Hong Kong University of Science and Technology
Xi Yao: City University of Hong Kong

Nature Communications, 2023, vol. 14, issue 1, 1-10

Abstract: Abstract The rapid-developing soft robots and wearable devices require flexible conductive materials to maintain electric functions over a large range of deformations. Considerable efforts are made to develop stretchable conductive materials; little attention is paid to the frequent failures of integrated circuits caused by the interface mismatch of soft substrates and rigid silicon-based microelectronics. Here, we present a stretchable solder with good weldability that can strongly bond with electronic components, benefiting from the hierarchical assemblies of liquid metal particles, small-molecule modulators, and non-covalently crosslinked polymer matrix. Our self-solder shows high conductivity (>2×105 S m−1), extreme stretchability (~1000%, and >600% with chip-integrated), and high toughness (~20 MJ m−3). Additionally, the dynamic interactions within our solder’s surface and interior enable a range of unique features, including ease of integration, component substitution, and circuit recyclability. With all these features, we demonstrated an application as thermoforming technology for three-dimensional (3D) conformable electronics, showing potential in reducing the complexity of microchip interfacing, as well as scalable fabrication of chip-integrated stretchable circuits and 3D electronics.

Date: 2023
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DOI: 10.1038/s41467-023-43574-8

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