Efficient, narrow-band, and stable electroluminescence from organoboron-nitrogen-carbonyl emitter
Ying-Chun Cheng,
Xun Tang,
Kai Wang (),
Xin Xiong,
Xiao-Chun Fan,
Shulin Luo,
Rajat Walia,
Yue Xie,
Tao Zhang,
Dandan Zhang,
Jia Yu,
Xian-Kai Chen (),
Chihaya Adachi () and
Xiao-Hong Zhang ()
Additional contact information
Ying-Chun Cheng: Soochow University
Xun Tang: Kyushu University
Kai Wang: Soochow University
Xin Xiong: Soochow University
Xiao-Chun Fan: Soochow University
Shulin Luo: Soochow University
Rajat Walia: Soochow University
Yue Xie: Soochow University
Tao Zhang: Soochow University
Dandan Zhang: Soochow University
Jia Yu: Soochow University
Xian-Kai Chen: Soochow University
Chihaya Adachi: Kyushu University
Xiao-Hong Zhang: Soochow University
Nature Communications, 2024, vol. 15, issue 1, 1-9
Abstract:
Abstract Organic light-emitting diodes (OLEDs) exploiting simple binary emissive layers (EMLs) blending only emitters and hosts have natural advantages in low-cost commercialization. However, previously reported OLEDs based on binary EMLs hardly simultaneously achieved desired comprehensive performances, e.g., high efficiency, low efficiency roll-off, narrow emission bands, and high operation stability. Here, we report a molecular-design strategy. Such a strategy leads to a fast reverse intersystem crossing rate in our designed emitter h-BNCO-1 of 1.79×105 s−1. An OLED exploiting a binary EML with h-BNCO-1 achieves ultrapure emission, a maximum external quantum efficiency of over 40% and a mild roll-off of 14% at 1000 cd·m−2. Moreover, h-BNCO-1 also exhibits promising operational stability in an alternative OLED exploiting a compact binary EML (the lifetime reaching 95% of the initial luminance at 1000 cd m−2 is ~ 137 h). Here, our work has thus provided a molecular-design strategy for OLEDs with promising comprehensive performance.
Date: 2024
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DOI: 10.1038/s41467-024-44981-1
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