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Free-standing two-dimensional ferro-ionic memristor

Jinhyoung Lee, Gunhoo Woo, Jinill Cho, Sihoon Son, Hyelim Shin, Hyunho Seok, Min-Jae Kim, Eungchul Kim, Ziyang Wang, Boseok Kang, Won-Jun Jang and Taesung Kim ()
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Jinhyoung Lee: Sungkyunkwan University (SKKU)
Gunhoo Woo: Sungkyunkwan University
Jinill Cho: Sungkyunkwan University (SKKU)
Sihoon Son: Sungkyunkwan University
Hyelim Shin: Sungkyunkwan University
Hyunho Seok: Sungkyunkwan University
Min-Jae Kim: Sungkyunkwan University
Eungchul Kim: Samsung Electronics
Ziyang Wang: Sungkyunkwan University (SKKU)
Boseok Kang: Sungkyunkwan University
Won-Jun Jang: Institute for Basic Science (IBS)
Taesung Kim: Sungkyunkwan University (SKKU)

Nature Communications, 2024, vol. 15, issue 1, 1-11

Abstract: Abstract Two-dimensional (2D) ferroelectric materials have emerged as significant platforms for multi-functional three-dimensional (3D) integrated electronic devices. Among 2D ferroelectric materials, ferro-ionic CuInP2S6 has the potential to achieve the versatile advances in neuromorphic computing systems due to its phase tunability and ferro-ionic characteristics. As CuInP2S6 exhibits a ferroelectric phase with insulating properties at room temperature, the external temperature and electrical field should be required to activate the ferro-ionic conduction. Nevertheless, such external conditions inevitably facilitate stochastic ionic conduction, which completely limits the practical applications of 2D ferro-ionic materials. Herein, free-standing 2D ferroelectric heterostructure is mechanically manipulated for nano-confined conductive filaments growth in free-standing 2D ferro-ionic memristor. The ultra-high mechanical bending is selectively facilitated at the free-standing area to spatially activate the ferro-ionic conduction, which allows the deterministic local positioning of Cu+ ion transport. According to the local flexoelectric engineering, 5.76×102-fold increased maximum current is observed within vertical shear strain 720 nN, which is theoretically supported by the 3D flexoelectric simulation. In conclusion, we envision that our universal free-standing platform can provide the extendable geometric solution for ultra-efficient self-powered system and reliable neuromorphic device.

Date: 2024
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DOI: 10.1038/s41467-024-48810-3

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