High-purity ethylene production via indirect carbon dioxide electrochemical reduction

Wenpeng Ni, Houjun Chen, Naizhuo Tang, Ting Hu, Wei Zhang, Yan Zhang and Shiguo Zhang ()
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Wenpeng Ni: Hunan University
Houjun Chen: Hunan University
Naizhuo Tang: Hunan University
Ting Hu: Hunan University
Wei Zhang: Hunan University
Yan Zhang: Hunan University
Shiguo Zhang: Hunan University

Nature Communications, 2024, vol. 15, issue 1, 1-12

Abstract: Abstract High-purity ethylene production from CO2 electroreduction (CO2RR) is a coveted, yet arduous feat because the product stream comprises a blend of unreacted CO2, H2, and other off-target CO2 reduction products. Here we present an indirect reduction strategy for CO2-to-ethylene conversion, one that employs 2-bromoethanol (Br-EO) as a mediator. Br-EO is initially generated from CO2RR and subsequently undergoes reduction to ethylene without the need for energy-intensive separation steps. The optimized AC-Ag/C catalyst with Cl incorporation reduces the energy barrier of the debromination step during Br-EO reduction, and accelerates the mass-transfer process, delivering a 4-fold decrease of the relaxation time constant. Resultantly, AC-Ag/C achieved a FEethylene of over 95.0 ± 0.36% at a low potential of −0.08 V versus reversible hydrogen electrode (RHE) in an H-type cell with 0.5 M KCl electrolyte, alongside a near 100% selectivity within the range of −0.38 to −0.58 V versus RHE. Through this indirect strategy, the average ethylene purity within 6-hour electrolysis was 98.00 ± 1.45 wt%, at −0.48 V (vs RHE) from the neutralized electrolyte after CO2 reduction over the Cu/Cu2O catalyst in a flow-cell.

Date: 2024
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DOI: 10.1038/s41467-024-50522-7

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