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Small signal analysis for the characterization of organic electrochemical transistors

Youngseok Kim (), Joost Kimpel, Alexander Giovannitti and Christian Müller ()
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Youngseok Kim: Chalmers University of Technology
Joost Kimpel: Chalmers University of Technology
Alexander Giovannitti: Chalmers University of Technology
Christian Müller: Chalmers University of Technology

Nature Communications, 2024, vol. 15, issue 1, 1-8

Abstract: Abstract A method for the characterization of organic electrochemical transistors (OECTs) based on small signal analysis is presented that allows to determine the electronic mobility as a function of continuous gate potential using a standard two-channel AC potentiostat. Vector analysis in the frequency domain allows to exclude parasitic components in both ionic and electronic conduction regardless of film thickness, thus resulting in a standard deviation as low as 4%. Besides the electronic mobility, small signal analysis of OECTs also provides information about a wide range of other parameters including the conductance, transconductance, conductivity and volumetric capacitance through a single measurement. General applicability of small signal analysis is demonstrated by characterizing devices based on n-type, p-type, and ambipolar materials operating in accumulation or depletion modes. Accurate benchmarking of organic mixed ionic-electronic conductors through small signal analysis can be anticipated to guide both materials development and the design of bioelectronic devices.

Date: 2024
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DOI: 10.1038/s41467-024-51883-9

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