Unraveling chemical origins of dendrite formation in zinc-ion batteries via in situ/operando X-ray spectroscopy and imaging

Hongliu Dai, Tianxiao Sun, Jigang Zhou (), Jian Wang (), Zhangsen Chen, Gaixia Zhang () and Shuhui Sun ()
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Hongliu Dai: Center Énergie Matériaux Télécommunications
Tianxiao Sun: Canadian Light Source
Jigang Zhou: Canadian Light Source
Jian Wang: Canadian Light Source
Zhangsen Chen: Center Énergie Matériaux Télécommunications
Gaixia Zhang: École de Technologie Supérieure (ÉTS)
Shuhui Sun: Center Énergie Matériaux Télécommunications

Nature Communications, 2024, vol. 15, issue 1, 1-13

Abstract: Abstract To prevent zinc (Zn) dendrite formation and improve electrochemical stability, it is essential to understand Zn dendrite growth, particularly in terms of morphology and relation with the solid electrolyte interface (SEI) film. In this study, we employ in-situ scanning transmission X-ray microscopy (STXM) and spectro-ptychography to monitor the morphology evolution of Zn dendrites and to identify their chemical composition and distribution on the Zn surface during the stripping/plating progress. Our findings reveal that in 50 mM ZnSO4, the initiation of moss/whisker dendrites is chemically controlled, while their continued growth over extended cycles is kinetically governed. The presence of a dense and stable SEI film is critical for inhibiting the formation and growth of Zn dendrites. By adding 50 mM lithium chloride (LiCl) as an electrolyte additive, we successfully construct a dense and stable SEI film composed of Li2S2O7 and Li2CO3, which significantly improves cycling performance. Moreover, the symmetric cell achieves a prolonged cycle life of up to 3900 h with the incorporation of 5% 12-crown-4 additives. This work offers a strategy for in-situ observation and analysis of Zn dendrite formation mechanisms and provides an effective approach for designing high-performance Zn-ion batteries.

Date: 2024
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DOI: 10.1038/s41467-024-52651-5

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