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Direct cleavage of C=O double bond in CO2 by the subnano MoOx surface on Mo2N

Hao-Xin Liu, Wei-Wei Wang (), Xin-Pu Fu, Jin-Cheng Liu () and Chun-Jiang Jia ()
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Hao-Xin Liu: Shandong University
Wei-Wei Wang: Shandong University
Xin-Pu Fu: Shandong University
Jin-Cheng Liu: Nankai University
Chun-Jiang Jia: Shandong University

Nature Communications, 2024, vol. 15, issue 1, 1-12

Abstract: Abstract Compared to H2-assisted activation mode, the direct dissociation of CO2 into carbonyl (*CO) with a simplified reaction route is advantageous for CO2-related synthetic processes and catalyst upgrading, while the stable C = O double bond makes it very challenging. Herein, we construct a subnano MoO3 layer on the surface of Mo2N, which provides a dynamically changing surface of MoO3↔MoOx (x

Date: 2024
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DOI: 10.1038/s41467-024-53484-y

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