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Ultra-low power-consumption OLEDs via phosphor-assisted thermally-activated-delayed-fluorescence-sensitized narrowband emission

Chen Yin, Yangyang Xin, Tianyu Huang, Qisheng Zhang, Lian Duan and Dongdong Zhang ()
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Chen Yin: Tsinghua University
Yangyang Xin: Tsinghua University
Tianyu Huang: Tsinghua University
Qisheng Zhang: Zhejiang University
Lian Duan: Tsinghua University
Dongdong Zhang: Tsinghua University

Nature Communications, 2025, vol. 16, issue 1, 1-12

Abstract: Abstract The further success of OLED beyond conventional low-luminance display applications has been hampered by the low power efficiency (PE) at high luminance. Here, we demonstrate the strategic implementation of an exceptionally high-PE, high-luminance OLED using a phosphor-assisted thermally-activated-delayed-fluorescence (TADF)-sensitized narrowband emission. On the basis of a TADF sensitizing-host possessing a fast reverse intersystem crossing, an anti-aggregation-caused-quenching character and a good bipolar charge-transporting ability, this design achieves not only a 100% exciton radiative consumption with decay times mainly in the sub-microsecond regime to mitigate exciton annihilations for nearly roll-off-free external quantum efficiency, but also narrowband emission with both small energetic loss during energy transfer and resistive loss with increasing luminance. Consequently, besides a maximum PE of 187.7 lm/W, an exceptionally high critical maximum luminance (where a PE of 100 lm/W is maintained) of over 110,000 cd/m2 is achieved for the proof-of-the-concept device, nearly one-of-magnitude higher than the previous record.

Date: 2025
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DOI: 10.1038/s41467-024-55564-5

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