Copper-catalyzed photoinduced carbonylation of C1-C3 gaseous alkanes

Le-Cheng Wang and Xiao-Feng Wu ()
Additional contact information
Le-Cheng Wang: Chinese Academy of Sciences
Xiao-Feng Wu: Chinese Academy of Sciences

Nature Communications, 2025, vol. 16, issue 1, 1-8

Abstract: Abstract The catalytic conversion of carbon monoxide (CO) provides an enormous opportunity to construct carbonyl-containing molecules. Among them, the direct carbonylation of C-H bonds on gaseous hydrocarbon feedstocks provides a straightforward approach to access industrially important short-chain carboxylic acid derivatives. Here, we report a general and mild direct carbonylation of methane, ethane, and propane under blue LED irradiation at ambient temperature, enabling the direct formation of short-chain carboxylic acid derivatives. Notably, the direct carbonylation of ethane offers the potential for a more cost-efficient route to produce MMA. The combination of copper reduction and chlorine radical released via a ligand-to-metal charge transfer (LMCT) process facilitates the activation of gaseous hydrocarbon in a mild and atom-economical mode.

Date: 2025
References: View complete reference list from CitEc
Citations:

Downloads: (external link)
https://www.nature.com/articles/s41467-025-58472-4 Abstract (text/html)

Related works:
This item may be available elsewhere in EconPapers: Search for items with the same title.

Export reference: BibTeX RIS (EndNote, ProCite, RefMan) HTML/Text

Persistent link: https://EconPapers.repec.org/RePEc:nat:natcom:v:16:y:2025:i:1:d:10.1038_s41467-025-58472-4

Ordering information: This journal article can be ordered from
https://www.nature.com/ncomms/

DOI: 10.1038/s41467-025-58472-4

Access Statistics for this article

Nature Communications is currently edited by Nathalie Le Bot, Enda Bergin and Fiona Gillespie

More articles in Nature Communications from Nature
Bibliographic data for series maintained by Sonal Shukla () and Springer Nature Abstracting and Indexing ().