Orbital-level band gap engineering of RuO2 for enhanced acidic water oxidation
Xing Wang,
Wei Pi,
Zhaobing Li,
Sheng Hu,
Haifeng Bao (),
Weilin Xu and
Na Yao ()
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Xing Wang: Wuhan Textile University
Wei Pi: Wuhan Textile University
Zhaobing Li: Wuhan Textile University
Sheng Hu: Wuhan Textile University
Haifeng Bao: Wuhan Textile University
Weilin Xu: Wuhan Textile University
Na Yao: Wuhan Textile University
Nature Communications, 2025, vol. 16, issue 1, 1-13
Abstract:
Abstract Developing efficient and stable oxygen evolution reaction electrocatalysts under acidic conditions is crucial for advancing proton-exchange membrane water electrolysers commercialization. Here, we develop a representative strategy through p-orbital atoms (N, P, S, Se) doping in RuO2 to precisely regulate the lattice oxygen-mediated mechanism-oxygen vacancy site mechanism pathway. In situ and ex situ measurements along with theoretical calculations demonstrate that Se doping dynamically adjusts the band gap between the Ru-eg and O-p orbitals during the oxygen evolution reaction process. This modulation accelerates electron diffusion to the external circuit, promotes the lattice oxygen-mediated process, and enhances catalytic activity. Additionally, it facilitates electron feedback and stabilizes oxygen vacancies, thereby promoting the oxygen vacancy site mechanism process and enhancing catalytic stability. The resulting Se-RuOx catalyst achieves efficient proton-exchange membrane water electrolysers performance under industrial conditions with a minimal charge overpotential of 1.67 V to achieve a current density of 1 A cm−2 and maintain long-term cyclability for over 1000 h. This work presents a unique method for guiding the future development of high-performance metal oxide catalysts.
Date: 2025
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Persistent link: https://EconPapers.repec.org/RePEc:nat:natcom:v:16:y:2025:i:1:d:10.1038_s41467-025-60083-y
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DOI: 10.1038/s41467-025-60083-y
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