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Trifunctional local-range order oxygen structure enhanced strength-ductility and fatigue resistance in large-scale metastable titanium alloy

Yamei Mao, Qinyang Zhao (), Runqi Zhang, Ping Guo, Yongnan Chen () and Yongqing Zhao
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Yamei Mao: Chang’an University
Qinyang Zhao: Chang’an University
Runqi Zhang: Northeastern University
Ping Guo: Northwest Institute for Non-ferrous Metal Research
Yongnan Chen: Chang’an University
Yongqing Zhao: Chang’an University

Nature Communications, 2025, vol. 16, issue 1, 1-11

Abstract: Abstract Research on high-performance Ti alloys incorporating oxygen (O) has remained a laboratory procedure and is hindered by the unresolved issue of O segregation-driven failure. Here, we demonstrate that O can tailor a nanoscale local range order O (LRO-O) structure between the oxide and random interstitials in Ti alloy. We introduce 0.36 wt% O into metastable Ti-5Al-5Mo-5V-3Cr alloy using a short-term powder metallurgy approach to produces large-scale materials. The LRO-O structure in designed alloy prevents crack initiation by promoting the active nucleation of -type dislocations and altering the slip modes during tensile and fatigue failure. The alloy has high strength (1.7 GPa), elongation (7.9%), and fatigue strength (1058.3 MPa), which outperforms many high-strength, high-O Ti alloys. Our findings provide a scalable, practical route to superior mechanical properties for Ti alloys without costly alloying elements.

Date: 2025
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DOI: 10.1038/s41467-025-62646-5

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