Colossal negative thermal expansion in BiNiO3 induced by intermetallic charge transfer

Masaki Azuma (), Wei-tin Chen, Hayato Seki, Michal Czapski, Smirnova Olga, Kengo Oka, Masaichiro Mizumaki, Tetsu Watanuki, Naoki Ishimatsu, Naomi Kawamura, Shintaro Ishiwata, Matthew G. Tucker, Yuichi Shimakawa and J. Paul Attfield
Additional contact information
Masaki Azuma: Institute for Chemical Research, Kyoto University, Uji, Kyoto 611-0011, Japan.
Wei-tin Chen: Institute for Chemical Research, Kyoto University, Uji, Kyoto 611-0011, Japan.
Hayato Seki: Institute for Chemical Research, Kyoto University, Uji, Kyoto 611-0011, Japan.
Michal Czapski: Institute for Chemical Research, Kyoto University, Uji, Kyoto 611-0011, Japan.
Smirnova Olga: Institute for Chemical Research, Kyoto University, Uji, Kyoto 611-0011, Japan.
Kengo Oka: Institute for Chemical Research, Kyoto University, Uji, Kyoto 611-0011, Japan.
Masaichiro Mizumaki: Japan Synchrotron Radiation Research Institute, 1-1-1 Kouto, Sayo, Hyogo 679-5198, Japan.
Tetsu Watanuki: Japan Atomic Energy Agency, 1-1-1 Kouto, Sayo, Hyogo 679-5148, Japan.
Naoki Ishimatsu: Graduate School of Science, Hiroshima University, 1-3-1 Kagamiyama, Higashi-Hiroshima 739-8526, Japan.
Naomi Kawamura: Japan Synchrotron Radiation Research Institute, 1-1-1 Kouto, Sayo, Hyogo 679-5198, Japan.
Shintaro Ishiwata: Institute for Chemical Research, Kyoto University, Uji, Kyoto 611-0011, Japan.
Matthew G. Tucker: ISIS facility, Rutherford Appleton Laboratory, Chilton, Didcot OX11 0QX, UK.
Yuichi Shimakawa: Institute for Chemical Research, Kyoto University, Uji, Kyoto 611-0011, Japan.
J. Paul Attfield: Centre for Science at Extreme Conditions and School of Chemistry, University of Edinburgh

Nature Communications, 2011, vol. 2, issue 1, 1-5

Abstract: Abstract The unusual property of negative thermal expansion is of fundamental interest and may be used to fabricate composites with zero or other controlled thermal expansion values. Here we report that colossal negative thermal expansion (defined as linear expansion

Date: 2011
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DOI: 10.1038/ncomms1361

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