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Repeated growth and bubbling transfer of graphene with millimetre-size single-crystal grains using platinum

Libo Gao, Wencai Ren, Huilong Xu, Li Jin, Zhenxing Wang, Teng Ma, Lai-Peng Ma, Zhiyong Zhang, Qiang Fu, Lian-Mao Peng, Xinhe Bao and Hui-Ming Cheng ()
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Libo Gao: Shenyang National Laboratory for Materials Science, Institute of Metal Research, Chinese Academy of Sciences
Wencai Ren: Shenyang National Laboratory for Materials Science, Institute of Metal Research, Chinese Academy of Sciences
Huilong Xu: Peking University
Li Jin: State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences
Zhenxing Wang: Peking University
Teng Ma: Shenyang National Laboratory for Materials Science, Institute of Metal Research, Chinese Academy of Sciences
Lai-Peng Ma: Shenyang National Laboratory for Materials Science, Institute of Metal Research, Chinese Academy of Sciences
Zhiyong Zhang: Peking University
Qiang Fu: State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences
Lian-Mao Peng: Peking University
Xinhe Bao: State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences
Hui-Ming Cheng: Shenyang National Laboratory for Materials Science, Institute of Metal Research, Chinese Academy of Sciences

Nature Communications, 2012, vol. 3, issue 1, 1-7

Abstract: Abstract Large single-crystal graphene is highly desired and important for the applications of graphene in electronics, as grain boundaries between graphene grains markedly degrade its quality and properties. Here we report the growth of millimetre-sized hexagonal single-crystal graphene and graphene films joined from such grains on Pt by ambient-pressure chemical vapour deposition. We report a bubbling method to transfer these single graphene grains and graphene films to arbitrary substrate, which is nondestructive not only to graphene, but also to the Pt substrates. The Pt substrates can be repeatedly used for graphene growth. The graphene shows high crystal quality with the reported lowest wrinkle height of 0.8 nm and a carrier mobility of greater than 7,100 cm2 V−1 s−1 under ambient conditions. The repeatable growth of graphene with large single-crystal grains on Pt and its nondestructive transfer may enable various applications.

Date: 2012
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DOI: 10.1038/ncomms1702

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