The biology and chemistry of high-valent iron–oxo and iron–nitrido complexes

Johannes Hohenberger, Kallol Ray () and Karsten Meyer ()
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Johannes Hohenberger: Inorganic Chemistry, Friedrich-Alexander-University Erlangen – Nuremberg
Kallol Ray: Humboldt-Universität zu Berlin
Karsten Meyer: Inorganic Chemistry, Friedrich-Alexander-University Erlangen – Nuremberg

Nature Communications, 2012, vol. 3, issue 1, 1-13

Abstract: High-valent iron–oxo and –nitrido complexes are intermediates in the catalytic cycles of various metalloenzymes that activate dioxygen and dinitrogen. Hohenbergeret al. review the advances in the chemistry of model high-valent iron–oxo and –nitrido systems and relate them to our understanding of related enzymes.

Date: 2012
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DOI: 10.1038/ncomms1718

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