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A non-syn-gas catalytic route to methanol production

Cheng-Tar Wu, Kai Man Kerry Yu, Fenglin Liao, Neil Young, Peter Nellist, Andrew Dent, Anna Kroner and Shik Chi Edman Tsang ()
Additional contact information
Cheng-Tar Wu: Wolfson Catalysis Centre, University of Oxford
Kai Man Kerry Yu: Wolfson Catalysis Centre, University of Oxford
Fenglin Liao: Wolfson Catalysis Centre, University of Oxford
Neil Young: University of Oxford
Peter Nellist: University of Oxford
Andrew Dent: Diamond Light Source Ltd, Harwell Science and Innovation Campus
Anna Kroner: Diamond Light Source Ltd, Harwell Science and Innovation Campus
Shik Chi Edman Tsang: Wolfson Catalysis Centre, University of Oxford

Nature Communications, 2012, vol. 3, issue 1, 1-8

Abstract: Abstract Methanol is an important platform molecule for chemical synthesis and its high energy density also renders it a good candidate as a cleaner transportation fuel. At present, methanol is manufactured from natural gas via the indirect syn-gas route. Here we show that ethylene glycol, a versatile chemical derived from biomass or fossil fuels, can be directly converted to methanol in hydrogen with high selectivity over a Pd/Fe2O3 co-precipitated catalyst. This opens up a possibility for diversification in natural resources for energy-starved countries. The working catalyst contains extremely small 'PdFe' clusters and metal adatoms on defective iron oxide to give the required metal-support interaction for the novel synthesis.

Date: 2012
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Persistent link: https://EconPapers.repec.org/RePEc:nat:natcom:v:3:y:2012:i:1:d:10.1038_ncomms2053

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DOI: 10.1038/ncomms2053

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