A seamless three-dimensional carbon nanotube graphene hybrid material
Yu Zhu,
Lei Li,
Chenguang Zhang,
Gilberto Casillas,
Zhengzong Sun,
Zheng Yan,
Gedeng Ruan,
Zhiwei Peng,
Abdul-Rahman O. Raji,
Carter Kittrell,
Robert H. Hauge and
James M. Tour ()
Additional contact information
Yu Zhu: Rice University
Lei Li: Rice University
Chenguang Zhang: Rice University
Gilberto Casillas: University of Texas at San Antonio
Zhengzong Sun: Rice University
Zheng Yan: Rice University
Gedeng Ruan: Rice University
Zhiwei Peng: Rice University
Abdul-Rahman O. Raji: Rice University
Carter Kittrell: Rice University
Robert H. Hauge: Rice University
James M. Tour: Rice University
Nature Communications, 2012, vol. 3, issue 1, 1-7
Abstract:
Abstract Graphene and single-walled carbon nanotubes are carbon materials that exhibit excellent electrical conductivities and large specific surface areas. Theoretical work suggested that a covalently bonded graphene/single-walled carbon nanotube hybrid material would extend those properties to three dimensions, and be useful in energy storage and nanoelectronic technologies. Here we disclose a method to bond graphene and single-walled carbon nanotubes seamlessly during the growth stage. The hybrid material exhibits a surface area >2,000 m2 g−1 with ohmic contact from the vertically aligned single-walled carbon nanotubes to the graphene. Using aberration-corrected scanning transmission electron microscopy, we observed the covalent transformation of sp2 carbon between the planar graphene and the single-walled carbon nanotubes at the atomic resolution level. These findings provide a new benchmark for understanding the three-dimensional graphene/single-walled carbon nanotube-conjoined materials.
Date: 2012
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Persistent link: https://EconPapers.repec.org/RePEc:nat:natcom:v:3:y:2012:i:1:d:10.1038_ncomms2234
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DOI: 10.1038/ncomms2234
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