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Ordered macroporous platinum electrode and enhanced mass transfer in fuel cells using inverse opal structure

Ok-Hee Kim, Yong-Hun Cho (), Soon Hyung Kang, Hee-Young Park, Minhyoung Kim, Ju Wan Lim, Dong Young Chung, Myeong Jae Lee, Heeman Choe and Yung-Eun Sung ()
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Ok-Hee Kim: Center for Nanoparticle Research, Institute for Basic Science (IBS)
Yong-Hun Cho: School of Advanced Materials Engineering, Kookmin University
Soon Hyung Kang: Chonnam National University
Hee-Young Park: Center for Nanoparticle Research, Institute for Basic Science (IBS)
Minhyoung Kim: Center for Nanoparticle Research, Institute for Basic Science (IBS)
Ju Wan Lim: Center for Nanoparticle Research, Institute for Basic Science (IBS)
Dong Young Chung: Center for Nanoparticle Research, Institute for Basic Science (IBS)
Myeong Jae Lee: Center for Nanoparticle Research, Institute for Basic Science (IBS)
Heeman Choe: School of Advanced Materials Engineering, Kookmin University
Yung-Eun Sung: Center for Nanoparticle Research, Institute for Basic Science (IBS)

Nature Communications, 2013, vol. 4, issue 1, 1-9

Abstract: Abstract Three-dimensional, ordered macroporous materials such as inverse opal structures are attractive materials for various applications in electrochemical devices because of the benefits derived from their periodic structures: relatively large surface areas, large voidage, low tortuosity and interconnected macropores. However, a direct application of an inverse opal structure in membrane electrode assemblies has been considered impractical because of the limitations in fabrication routes including an unsuitable substrate. Here we report the demonstration of a single cell that maintains an inverse opal structure entirely within a membrane electrode assembly. Compared with the conventional catalyst slurry, an ink-based assembly, this modified assembly has a robust and integrated configuration of catalyst layers; therefore, the loss of catalyst particles can be minimized. Furthermore, the inverse-opal-structure electrode maintains an effective porosity, an enhanced performance, as well as an improved mass transfer and more effective water management, owing to its morphological advantages.

Date: 2013
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Persistent link: https://EconPapers.repec.org/RePEc:nat:natcom:v:4:y:2013:i:1:d:10.1038_ncomms3473

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DOI: 10.1038/ncomms3473

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