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Correlating interfacial octahedral rotations with magnetism in (LaMnO3+δ)N/(SrTiO3)N superlattices

Xiaofang Zhai (), Long Cheng, Yang Liu (), Christian M. Schlepütz, Shuai Dong (), Hui Li, Xiaoqiang Zhang, Shengqi Chu, Lirong Zheng, Jing Zhang, Aidi Zhao, Hawoong Hong, Anand Bhattacharya, James N. Eckstein and Changgan Zeng
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Xiaofang Zhai: Hefei National Laboratory for Physical Sciences at the Microscale, University of Science and Technology of China
Long Cheng: Hefei National Laboratory for Physical Sciences at the Microscale, University of Science and Technology of China
Yang Liu: Argonne National Laboratory
Christian M. Schlepütz: Argonne National Laboratory
Shuai Dong: Southeast University
Hui Li: Hefei National Laboratory for Physical Sciences at the Microscale, University of Science and Technology of China
Xiaoqiang Zhang: Hefei National Laboratory for Physical Sciences at the Microscale, University of Science and Technology of China
Shengqi Chu: Beijing Synchrotron Radiation Facility, Institute of High Energy Physics, Chinese Academy of Sciences
Lirong Zheng: Beijing Synchrotron Radiation Facility, Institute of High Energy Physics, Chinese Academy of Sciences
Jing Zhang: Beijing Synchrotron Radiation Facility, Institute of High Energy Physics, Chinese Academy of Sciences
Aidi Zhao: Synergetic Innovation Center of Quantum Information and Quantum Physics, University of Science and Technology of China
Hawoong Hong: Argonne National Laboratory
Anand Bhattacharya: Argonne National Laboratory
James N. Eckstein: University of Illinois at Urbana-Champaign
Changgan Zeng: Hefei National Laboratory for Physical Sciences at the Microscale, University of Science and Technology of China

Nature Communications, 2014, vol. 5, issue 1, 1-8

Abstract: Abstract Lattice distortion due to oxygen octahedral rotations have a significant role in mediating the magnetism in oxides, and recently attracts a lot of interests in the study of complex oxides interface. However, the direct experimental evidence for the interrelation between octahedral rotation and magnetism at interface is scarce. Here we demonstrate that interfacial octahedral rotation are closely linked to the strongly modified ferromagnetism in (LaMnO3+δ)N/(SrTiO3)N superlattices. The maximized ferromagnetic moment in the N=6 superlattice is accompanied by a metastable structure (space group Imcm) featuring minimal octahedral rotations (a−a−c−, α~4.2°, γ~0.5°). Quenched ferromagnetism for N

Date: 2014
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DOI: 10.1038/ncomms5283

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