Trinucleotide duplex formation inside a confined nanospace under supercooled conditions

Hiroyuki Arafune, Akira Yamaguchi (), Manato Namekawa, Yusuke Sato, Tetsuji Itoh, Ryoko Yoshida and Norio Teramae ()
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Hiroyuki Arafune: Graduate School of Science, Tohoku University
Akira Yamaguchi: College of Science, Ibaraki University
Manato Namekawa: Graduate School of Science, Tohoku University
Yusuke Sato: Graduate School of Science, Tohoku University
Tetsuji Itoh: Research Center for Compact Chemical System, National Institute of Advanced Industrial Science and Technology (AIST)
Ryoko Yoshida: College of Science, Ibaraki University
Norio Teramae: Graduate School of Science, Tohoku University

Nature Communications, 2014, vol. 5, issue 1, 1-7

Abstract: Abstract Self-assembly of nucleotides of fewer than three base pairs is often found in protein–nucleotide conjugations, despite their energetic instability, and is regarded as the potential starting point for the creation of artificial hydrogen-bonded supramolecular complexes. Here we report duplex formation of 3-mer DNA fragments confined within silica mesopores modified with a positively charged trimethyl aminopropyl monolayer, and their further stabilization under supercooled conditions (T

Date: 2014
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DOI: 10.1038/ncomms6151

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