Positioning and joining of organic single-crystalline wires
Yuchen Wu,
Jiangang Feng,
Xiangyu Jiang,
Zhen Zhang,
Xuedong Wang,
Bin Su () and
Lei Jiang ()
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Yuchen Wu: Beijing National Laboratory for Molecular Science (BNLMS), Key Laboratory of Organic Solids, Institute of Chemistry, Chinese Academy of Sciences
Jiangang Feng: Beijing National Laboratory for Molecular Science (BNLMS), Key Laboratory of Organic Solids, Institute of Chemistry, Chinese Academy of Sciences
Xiangyu Jiang: Beijing National Laboratory for Molecular Science (BNLMS), Key Laboratory of Organic Solids, Institute of Chemistry, Chinese Academy of Sciences
Zhen Zhang: Beijing National Laboratory for Molecular Science (BNLMS), Key Laboratory of Organic Solids, Institute of Chemistry, Chinese Academy of Sciences
Xuedong Wang: Beijing National Laboratory for Molecular Science (BNLMS), Key Laboratory of Organic Solids, Institute of Chemistry, Chinese Academy of Sciences
Bin Su: Beijing National Laboratory for Molecular Science (BNLMS), Key Laboratory of Organic Solids, Institute of Chemistry, Chinese Academy of Sciences
Lei Jiang: Beijing National Laboratory for Molecular Science (BNLMS), Key Laboratory of Organic Solids, Institute of Chemistry, Chinese Academy of Sciences
Nature Communications, 2015, vol. 6, issue 1, 1-10
Abstract:
Abstract Organic single-crystal, one-dimensional materials can effectively carry charges and/or excitons due to their highly ordered molecule packing, minimized defects and eliminated grain boundaries. Controlling the alignment/position of organic single-crystal one-dimensional architectures would allow on-demand photon/electron transport, which is a prerequisite in waveguides and other optoelectronic applications. Here we report a guided physical vapour transport technique to control the growth, alignment and positioning of organic single-crystal wires with the guidance of pillar-structured substrates. Submicrometre-wide, hundreds of micrometres long, highly aligned, organic single-crystal wire arrays are generated. Furthermore, these organic single-crystal wires can be joined within controlled angles by varying the pillar geometries. Owing to the controllable growth of organic single-crystal one-dimensional architectures, we can present proof-of-principle demonstrations utilizing joined wires to allow optical waveguide through small radii of curvature (internal angles of ~90–120°). Our methodology may open a route to control the growth of organic single-crystal one-dimensional materials with potential applications in optoelectronics.
Date: 2015
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Persistent link: https://EconPapers.repec.org/RePEc:nat:natcom:v:6:y:2015:i:1:d:10.1038_ncomms7737
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DOI: 10.1038/ncomms7737
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