The water catalysis at oxygen cathodes of lithium–oxygen cells

Fujun Li, Shichao Wu, Li De, Tao Zhang, Ping He, Atsuo Yamada and Haoshen Zhou ()
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Fujun Li: Energy Interface Technology Group, National Institute of Advanced Industrial Science and Technology (AIST)
Shichao Wu: Energy Interface Technology Group, National Institute of Advanced Industrial Science and Technology (AIST)
Li De: Energy Interface Technology Group, National Institute of Advanced Industrial Science and Technology (AIST)
Tao Zhang: Energy Interface Technology Group, National Institute of Advanced Industrial Science and Technology (AIST)
Ping He: National Laboratory of Solid State Microstructures & College of Engineering and Applied Sciences, Nanjing University
Atsuo Yamada: The University of Tokyo
Haoshen Zhou: Energy Interface Technology Group, National Institute of Advanced Industrial Science and Technology (AIST)

Nature Communications, 2015, vol. 6, issue 1, 1-7

Abstract: Abstract Lithium–oxygen cells have attracted extensive interests due to their high theoretical energy densities. The main challenges are the low round-trip efficiency and cycling instability over long time. However, even in the state-of-the-art lithium–oxygen cells the charge potentials are as high as 3.5 V that are higher by 0.70 V than the discharge potentials. Here we report a reaction mechanism at an oxygen cathode, ruthenium and manganese dioxide nanoparticles supported on carbon black Super P by applying a trace amount of water in electrolytes to catalyse the cathode reactions of lithium–oxygen cells during discharge and charge. This can significantly reduce the charge overpotential to 0.21 V, and results in a small discharge/charge potential gap of 0.32 V and superior cycling stability of 200 cycles. The overall reaction scheme will alleviate side reactions involving carbon and electrolytes, and shed light on the construction of practical, rechargeable lithium–oxygen cells.

Date: 2015
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DOI: 10.1038/ncomms8843

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