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Stable ultrathin partially oxidized copper film electrode for highly efficient flexible solar cells

Guoqing Zhao, Wei Wang, Tae-Sung Bae, Sang-Geul Lee, ChaeWon Mun, Sunghun Lee, Huashun Yu, Gun-Hwan Lee, Myungkwan Song () and Jungheum Yun ()
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Guoqing Zhao: Key Laboratory for Liquid-Solid Structural Evolution and Processing of Materials, School of Materials Science and Engineering, Shandong University
Wei Wang: Institute of Hybrid Materials, The Growing Base for State Key Laboratory, Qingdao University
Tae-Sung Bae: Jeonju Center, Korea Basic Science Institute
Sang-Geul Lee: Daegu Center, Korea Basic Science Institute
ChaeWon Mun: Korea Institute of Materials Science
Sunghun Lee: Korea Institute of Materials Science
Huashun Yu: Key Laboratory for Liquid-Solid Structural Evolution and Processing of Materials, School of Materials Science and Engineering, Shandong University
Gun-Hwan Lee: Korea Institute of Materials Science
Myungkwan Song: Korea Institute of Materials Science
Jungheum Yun: Korea Institute of Materials Science

Nature Communications, 2015, vol. 6, issue 1, 1-8

Abstract: Abstract Advances in flexible optoelectronic devices have led to an increasing need for developing highly efficient, low-cost, flexible transparent conducting electrodes. Copper-based electrodes have been unattainable due to the relatively low optical transmission and poor oxidation resistance of copper. Here, we report the synthesis of a completely continuous, smooth copper ultra-thin film via limited copper oxidation with a trace amount of oxygen. The weakly oxidized copper thin film sandwiched between zinc oxide films exhibits good optoelectrical performance (an average transmittance of 83% over the visible spectral range of 400–800 nm and a sheet resistance of 9 Ω sq−1) and strong oxidation resistance. These values surpass those previously reported for copper-based electrodes; further, the record power conversion efficiency of 7.5% makes it clear that the use of an oxidized copper-based transparent electrode on a polymer substrate can provide an effective solution for the fabrication of flexible organic solar cells.

Date: 2015
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DOI: 10.1038/ncomms9830

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