Giant elastic tunability in strained BiFeO3 near an electrically induced phase transition

Q Li, Y. Cao, P. Yu, R. K. Vasudevan, N. Laanait, A. Tselev, F. Xue, L. Q. Chen, P. Maksymovych, S. V. Kalinin and N. Balke ()
Additional contact information
Q Li: Center for Nanophase Materials Sciences and Institute for Functional Imaging of Materials, Oak Ridge National Laboratory
Y. Cao: Center for Nanophase Materials Sciences and Institute for Functional Imaging of Materials, Oak Ridge National Laboratory
P. Yu: State Key Laboratory for Low-Dimensional Quantum Physics, Tsinghua University
R. K. Vasudevan: Center for Nanophase Materials Sciences and Institute for Functional Imaging of Materials, Oak Ridge National Laboratory
N. Laanait: Center for Nanophase Materials Sciences and Institute for Functional Imaging of Materials, Oak Ridge National Laboratory
A. Tselev: Center for Nanophase Materials Sciences and Institute for Functional Imaging of Materials, Oak Ridge National Laboratory
F. Xue: Pennsylvania State University, University Park
L. Q. Chen: Pennsylvania State University, University Park
P. Maksymovych: Center for Nanophase Materials Sciences and Institute for Functional Imaging of Materials, Oak Ridge National Laboratory
S. V. Kalinin: Center for Nanophase Materials Sciences and Institute for Functional Imaging of Materials, Oak Ridge National Laboratory
N. Balke: Center for Nanophase Materials Sciences and Institute for Functional Imaging of Materials, Oak Ridge National Laboratory

Nature Communications, 2015, vol. 6, issue 1, 1-9

Abstract: Abstract Elastic anomalies are signatures of phase transitions in condensed matters and have traditionally been studied using various techniques spanning from neutron scattering to static mechanical testing. Here, using band-excitation elastic/piezoresponse spectroscopy, we probed sub-MHz elastic dynamics of a tip bias-induced rhombohedral−tetragonal phase transition of strained (001)-BiFeO3 (rhombohedral) ferroelectric thin films from ∼103 nm3 sample volumes. Near this transition, we observed that the Young’s modulus intrinsically softens by over 30% coinciding with two- to three-fold enhancement of local piezoresponse. Coupled with phase-field modelling, we also addressed the influence of polarization switching and mesoscopic structural heterogeneities (for example, domain walls) on the kinetics of this phase transition, thereby providing fresh insights into the morphotropic phase boundary in ferroelectrics. Furthermore, the giant electrically tunable elastic stiffness and corresponding electromechanical properties observed here suggest potential applications of BiFeO3 in next-generation frequency-agile electroacoustic devices, based on the utilization of the soft modes underlying successive ferroelectric phase transitions.

Date: 2015
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DOI: 10.1038/ncomms9985

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