Explanation of efficient quenching of molecular ion vibrational motion by ultracold atoms

Thierry Stoecklin (), Philippe Halvick, Mohamed Achref Gannouni, Majdi Hochlaf, Svetlana Kotochigova and Eric R. Hudson
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Thierry Stoecklin: Université de Bordeaux, Institut des Sciences Moléculaires
Philippe Halvick: Université de Bordeaux, Institut des Sciences Moléculaires
Mohamed Achref Gannouni: Université Paris-Est, Laboratoire Modélisation et Simulation Multi Echelle
Majdi Hochlaf: Université Paris-Est, Laboratoire Modélisation et Simulation Multi Echelle
Svetlana Kotochigova: Temple University
Eric R. Hudson: University of California

Nature Communications, 2016, vol. 7, issue 1, 1-8

Abstract: Abstract Buffer gas cooling of molecules to cold and ultracold temperatures is a promising technique for realizing a host of scientific and technological opportunities. Unfortunately, experiments using cryogenic buffer gases have found that although the molecular motion and rotation are quickly cooled, the molecular vibration relaxes at impractically long timescales. Here, we theoretically explain the recently observed exception to this rule: efficient vibrational cooling of BaCl+ by a laser-cooled Ca buffer gas. We perform intense close-coupling calculations that agree with the experimental result, and use both quantum defect theory and a statistical capture model to provide an intuitive understanding of the system. This result establishes that, in contrast to the commonly held opinion, there exists a large class of systems that exhibit efficient vibrational cooling and therefore supports a new route to realize the long-sought opportunities offered by molecular structure.

Date: 2016
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DOI: 10.1038/ncomms11234

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