Formation of metallic cation-oxygen network for anomalous thermal expansion coefficients in binary phosphate glass

Yohei Onodera, Shinji Kohara (), Hirokazu Masai (), Akitoshi Koreeda, Shun Okamura and Takahiro Ohkubo
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Yohei Onodera: Research Reactor Institute
Shinji Kohara: Light/Quantum Beam Field, Research Center for Advanced Measurement and Characterization, National Institute for Materials Science (NIMS)
Hirokazu Masai: Institute for Chemical Research, Kyoto University
Akitoshi Koreeda: Ritsumeikan University
Shun Okamura: Institute for Chemical Research, Kyoto University
Takahiro Ohkubo: Graduate School & Faculty of Engineering, Chiba University

Nature Communications, 2017, vol. 8, issue 1, 1-8

Abstract: Abstract Understanding glass structure is still challenging due to the result of disorder, although novel materials design on the basis of atomistic structure has been strongly demanded. Here we report on the atomic structures of the zinc phosphate glass determined by reverse Monte Carlo modelling based on diffraction and spectroscopic data. The zinc-rich glass exhibits the network formed by ZnOx (averaged x

Date: 2017
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DOI: 10.1038/ncomms15449

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