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Black phosphorus ink formulation for inkjet printing of optoelectronics and photonics

Guohua Hu, Tom Albrow-Owen, Xinxin Jin, Ayaz Ali, Yuwei Hu, Richard C. T. Howe, Khurram Shehzad, Zongyin Yang, Xuekun Zhu, Robert I. Woodward, Tien-Chun Wu, Henri Jussila, Jiang-Bin Wu, Peng Peng, Ping-Heng Tan, Zhipei Sun, Edmund J. R. Kelleher, Meng Zhang (), Yang Xu () and Tawfique Hasan ()
Additional contact information
Guohua Hu: University of Cambridge
Tom Albrow-Owen: University of Cambridge
Xinxin Jin: Beihang University
Ayaz Ali: Zhejiang University
Yuwei Hu: Beihang University
Richard C. T. Howe: University of Cambridge
Khurram Shehzad: Zhejiang University
Zongyin Yang: University of Cambridge
Xuekun Zhu: Beihang University
Robert I. Woodward: Imperial College London
Tien-Chun Wu: University of Cambridge
Henri Jussila: Aalto University
Jiang-Bin Wu: Chinese Academy of Sciences
Peng Peng: Beihang University
Ping-Heng Tan: Chinese Academy of Sciences
Zhipei Sun: Aalto University
Edmund J. R. Kelleher: Imperial College London
Meng Zhang: Beihang University
Yang Xu: Zhejiang University
Tawfique Hasan: University of Cambridge

Nature Communications, 2017, vol. 8, issue 1, 1-10

Abstract: Abstract Black phosphorus is a two-dimensional material of great interest, in part because of its high carrier mobility and thickness dependent direct bandgap. However, its instability under ambient conditions limits material deposition options for device fabrication. Here we show a black phosphorus ink that can be reliably inkjet printed, enabling scalable development of optoelectronic and photonic devices. Our binder-free ink suppresses coffee ring formation through induced recirculating Marangoni flow, and supports excellent consistency ( 30 days) oxidation. We demonstrate printed black phosphorus as a passive switch for ultrafast lasers, stable against intense irradiation, and as a visible to near-infrared photodetector with high responsivities. Our work highlights the promise of this material as a functional ink platform for printed devices.

Date: 2017
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DOI: 10.1038/s41467-017-00358-1

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