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Strain-shear coupling in bilayer MoS2

Jae-Ung Lee, Sungjong Woo, Jaesung Park, Hee Chul Park, Young-Woo Son () and Hyeonsik Cheong ()
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Jae-Ung Lee: Sogang University
Sungjong Woo: Korea Institute for Advanced Study
Jaesung Park: Sogang University
Hee Chul Park: Korea Institute for Advanced Study
Young-Woo Son: Korea Institute for Advanced Study
Hyeonsik Cheong: Sogang University

Nature Communications, 2017, vol. 8, issue 1, 1-7

Abstract: Abstract Layered materials such as graphite and transition metal dichalcogenides have extremely anisotropic mechanical properties owing to orders of magnitude difference between in-plane and out-of-plane interatomic interaction strengths. Although effects of mechanical perturbations on either intralayer or interlayer interactions have been extensively investigated, mutual correlations between them have rarely been addressed. Here, we show that layered materials have an inevitable coupling between in-plane uniaxial strain and interlayer shear. Because of this, the uniaxial in-plane strain induces an anomalous splitting of the degenerate interlayer shear phonon modes such that the split shear mode along the tensile strain is not softened but hardened contrary to the case of intralayer phonon modes. We confirm the effect by measuring Raman shifts of shear modes of bilayer MoS2 under strain. Moreover, by analyzing the splitting, we obtain an unexplored off-diagonal elastic constant, demonstrating that Raman spectroscopy can determine almost all mechanical constants of layered materials.

Date: 2017
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DOI: 10.1038/s41467-017-01487-3

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