Calculating curly arrows from ab initio wavefunctions

Yu Liu, Philip Kilby, Terry J. Frankcombe and Timothy W. Schmidt ()
Additional contact information
Yu Liu: UNSW Sydney
Philip Kilby: Data 61
Terry J. Frankcombe: UNSW Canberra
Timothy W. Schmidt: UNSW Sydney

Nature Communications, 2018, vol. 9, issue 1, 1-7

Abstract: Abstract Despite being at the heart of chemical thought, the curly arrow notation of reaction mechanisms has been treated with suspicion—the connection with rigorous molecular quantum mechanics being unclear. The connection requires a view of the wavefunction that goes beyond molecular orbitals and rests on the most fundamental property of electrons. The antisymmetry of electronic wavefunctions requires that an N-electron wavefunction repeat itself in 3N dimensions, thus exhibiting tiles. Inspection of wavefunction tiles permits insight into structure and mechanism. Here, we demonstrate that analysis of the wavefunction tile along a reaction coordinate reveals the electron movements depicted by the curly arrow notation for several reactions. The Diels–Alder reaction is revealed to involve the separation and counter propagation of electron spins. This unprecedented method of extracting the movements of electrons during a chemical reaction is a breakthrough in connecting traditional depictions of chemical mechanism with state-of-the-art quantum chemical calculations.

Date: 2018
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DOI: 10.1038/s41467-018-03860-2

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