Solvent-assisted programming of flat polymer sheets into reconfigurable and self-healing 3D structures
Yang Yang,
Eugene M. Terentjev,
Yen Wei and
Yan Ji ()
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Yang Yang: Tsinghua University
Eugene M. Terentjev: University of Cambridge
Yen Wei: Tsinghua University
Yan Ji: Tsinghua University
Nature Communications, 2018, vol. 9, issue 1, 1-7
Abstract:
Abstract It is extremely challenging, yet critically desirable to convert 2D plastic films into 3D structures without any assisting equipment. Taking the advantage of solvent-induced bond-exchange reaction and elastic-plastic transition, shape programming of flat vitrimer polymer sheets offers a new way to obtain 3D structures or topologies, which are hard for traditional molding to achieve. Here we show that such programming can be achieved with a pipette, a hair dryer, and a bottle of solvent. The polymer used here is very similar to the commercial epoxy, except that a small percentage of a specific catalyst is involved to facilitate the bond-exchange reaction. The programmed 3D structures can later be erased, reprogrammed, welded with others, and healed again and again, using the same solvent-assisted technique. The 3D structures can also be recycled by hot-pressing into new sheets, which can still be repeatedly programmed.
Date: 2018
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Persistent link: https://EconPapers.repec.org/RePEc:nat:natcom:v:9:y:2018:i:1:d:10.1038_s41467-018-04257-x
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DOI: 10.1038/s41467-018-04257-x
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