EconPapers    
Economics at your fingertips  
 

High-performance sodium–organic battery by realizing four-sodium storage in disodium rhodizonate

Minah Lee, Jihyun Hong, Jeffrey Lopez, Yongming Sun, Dawei Feng, Kipil Lim, William C. Chueh, Michael F. Toney, Yi Cui () and Zhenan Bao ()
Additional contact information
Minah Lee: Stanford University
Jihyun Hong: Stanford University
Jeffrey Lopez: Stanford University
Yongming Sun: Stanford University
Dawei Feng: Stanford University
Kipil Lim: Stanford University
William C. Chueh: Stanford University
Michael F. Toney: SLAC National Accelerator Laboratory
Yi Cui: Stanford University
Zhenan Bao: Stanford University

Nature Energy, 2017, vol. 2, issue 11, 861-868

Abstract: Abstract Sodium-ion batteries (SIBs) for grid-scale applications need active materials that combine a high energy density with sustainability. Given the high theoretical specific capacity 501 mAh g−1, and Earth abundance of disodium rhodizonate (Na2C6O6), it is one of the most promising cathodes for SIBs. However, substantially lower reversible capacities have been obtained compared with the theoretical value and the understanding of this discrepancy has been limited. Here, we reveal that irreversible phase transformation of Na2C6O6 during cycling is the origin of the deteriorating redox activity of Na2C6O6. The active-particle size and electrolyte conditions were identified as key factors to decrease the activation barrier of the phase transformation during desodiation. On the basis of this understanding, we achieved four-sodium storage in a Na2C6O6 electrode with a reversible capacity of 484 mAh g−1, an energy density of 726 Wh kg−1 cathode, an energy efficiency above 87% and a good cycle retention.

Date: 2017
References: Add references at CitEc
Citations: View citations in EconPapers (2)

Downloads: (external link)
https://www.nature.com/articles/s41560-017-0014-y Abstract (text/html)
Access to the full text of the articles in this series is restricted.

Related works:
This item may be available elsewhere in EconPapers: Search for items with the same title.

Export reference: BibTeX RIS (EndNote, ProCite, RefMan) HTML/Text

Persistent link: https://EconPapers.repec.org/RePEc:nat:natene:v:2:y:2017:i:11:d:10.1038_s41560-017-0014-y

Ordering information: This journal article can be ordered from
https://www.nature.com/nenergy/

DOI: 10.1038/s41560-017-0014-y

Access Statistics for this article

Nature Energy is currently edited by Fouad Khan

More articles in Nature Energy from Nature
Bibliographic data for series maintained by Sonal Shukla () and Springer Nature Abstracting and Indexing ().

 
Page updated 2025-03-19
Handle: RePEc:nat:natene:v:2:y:2017:i:11:d:10.1038_s41560-017-0014-y