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Generalized Ehrenfest's approach to phase transitions in multicomponent systems in the presence of an electromagnetic field

L. Ambrosone () and F. Fontana

The European Physical Journal B: Condensed Matter and Complex Systems, 2005, vol. 48, issue 4, 537-545

Abstract: The path of a transformation is defined and discussed in the framework of classical thermodynamics. The Ehrenfest's approach to the theory of higher order transition is generalized to heterogeneous systems of r components in the presence and in the absence of electromagnetic fields. By introducing a state label the phase transitions, in proximity of singular points, are analysed in terms of the stability theory. Systems, in the presence and in the absence of a magnetic field are discussed in some detail. It is shown that the Ehrenfest approximation about the transition of 2nd order is physically unstable. Copyright EDP Sciences/Società Italiana di Fisica/Springer-Verlag 2005

Date: 2005
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DOI: 10.1140/epjb/e2006-00005-5

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