Energy diffusion controlled reaction rate of reacting particle driven by broad-band noise

M. L. Deng and W. Q. Zhu ()

The European Physical Journal B: Condensed Matter and Complex Systems, 2007, vol. 59, issue 3, 391-397

Abstract: The energy diffusion controlled reaction rate of a reacting particle with linear weak damping and broad-band noise excitation is studied by using the stochastic averaging method. First, the stochastic averaging method for strongly nonlinear oscillators under broad-band noise excitation using generalized harmonic functions is briefly introduced. Then, the reaction rate of the classical Kramers' reacting model with linear weak damping and broad-band noise excitation is investigated by using the stochastic averaging method. The averaged Itô stochastic differential equation describing the energy diffusion and the Pontryagin equation governing the mean first-passage time (MFPT) are established. The energy diffusion controlled reaction rate is obtained as the inverse of the MFPT by solving the Pontryagin equation. The results of two special cases of broad-band noises, i.e. the harmonic noise and the exponentially corrected noise, are discussed in details. It is demonstrated that the general expression of reaction rate derived by the authors can be reduced to the classical ones via linear approximation and high potential barrier approximation. The good agreement with the results of the Monte Carlo simulation verifies that the reaction rate can be well predicted using the stochastic averaging method. Copyright EDP Sciences/Società Italiana di Fisica/Springer-Verlag 2007

Keywords: 02.50.-r Probability theory; stochastic processes; and statistics; 05.40.-a Fluctuation phenomena; random processes; noise; and Brownian motion; 05.45.-a Nonlinear dynamics and chaos (search for similar items in EconPapers)
Date: 2007
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DOI: 10.1140/epjb/e2007-00290-4

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