SEGREGATION EFFECTS IN THE OXYGEN/CYCLOHEXANE/Ni{111} COADSORPTION SYSTEM

E. Cooper and R. Raval
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E. Cooper: Leverhulme Centre, Department of Chemistry and IRC in Surface Science, University of Liverpool, P.O. Box 147, Liverpool L69 3BX, UK
R. Raval: Leverhulme Centre, Department of Chemistry and IRC in Surface Science, University of Liverpool, P.O. Box 147, Liverpool L69 3BX, UK

Surface Review and Letters (SRL), 1994, vol. 01, issue 04, 465-468

Abstract: The coadsorption of cyclohexane and oxygen on Ni{111} at 110 K was studied using reflectionadsorption infrared spectroscopy (RAIRS). The effect of postdosed oxygen on the cyclohexane adlayer can be understood in terms of repulsive oxygen-cyclohexane interactions which lead to segregation and compression of the cyclohexane islands.

Date: 1994
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DOI: 10.1142/S0218625X94000448

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