DISSOCIATIVE ADSORPTION OF NO AND REACTIONS OFNO2ON ROUGH SILVER SURFACES

F. Bartolucci and A. Otto
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F. Bartolucci: Lehrstuhl für Oberflächenwissenschaft (IPkM), Heinrich-Heine- Universität Düsseldorf 40225 Düsseldorf, Germany
A. Otto: Lehrstuhl für Oberflächenwissenschaft (IPkM), Heinrich-Heine- Universität Düsseldorf 40225 Düsseldorf, Germany

Surface Review and Letters (SRL), 1994, vol. 01, issue 04, 561-564

Abstract: The transformation of NO andNO2on cold-deposited silver films (30-40 K) has been investigated by SERS under UHV conditions. After exposure with doses of NO we observed strong signals of${\rm{NO}}_2^ - $,N2O, and atomic oxygen and weak signals of physisorbedN2but none of NO. The reactions ofNO2on the surface are exposure dependent and yields the formation of${\rm{NO}}_2^ - $,${\rm{NO}}_3^ - $, and the dimerised speciesN2O4.

Date: 1994
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DOI: 10.1142/S0218625X94000667

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