THE INTERACTION OF METHANOL WITH CLEAN AND OXYGEN-PRECOVEREDAg{111}: A RAIRS STUDY

W.S. Sim, P. Gardner and D.A. King
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W.S. Sim: Department of Chemistry, University of Cambridge, Lensfield Road, Cambridge CB2 1EW, UK
P. Gardner: Department of Chemistry, University of Cambridge, Lensfield Road, Cambridge CB2 1EW, UK
D.A. King: Department of Chemistry, University of Cambridge, Lensfield Road, Cambridge CB2 1EW, UK

Surface Review and Letters (SRL), 1994, vol. 01, issue 04, 673-676

Abstract: The adsorption of methanol on clean and oxygen-precoveredAg{111}has been investigated by high-resolution infrared spectroscopy. On the clean surface a highly inclined, associatively adsorbed methanol overlayer was detected. The presence of coadsorbed atomic oxygen results in the formation of a surface methoxy species, which is shown to have its C-O bond axis oriented normal to the surface by the application of the metal-surface selection rule.

Date: 1994
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DOI: 10.1142/S0218625X94000916

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