DISSOCIATIVE CHEMISORPTION OFH2(D2)AT Fe(110)

A. Wight, A. Hodgson, G. Worthy, D. Butler and B.E. Hayden
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A. Wight: Surface Science Research Centre, University of Liverpool, P.O. Box 147, Liverpool L69 3BX, UK
A. Hodgson: Surface Science Research Centre, University of Liverpool, P.O. Box 147, Liverpool L69 3BX, UK
G. Worthy: Surface Science Research Centre, University of Liverpool, P.O. Box 147, Liverpool L69 3BX, UK
D. Butler: Department of Chemistry, Southampton University, Highfield, Southampton SO9 5NH, UK
B.E. Hayden: Department of Chemistry, Southampton University, Highfield, Southampton SO9 5NH, UK

Surface Review and Letters (SRL), 1994, vol. 01, issue 04, 693-696

Abstract: The dissociative chemisorption ofH2(D2)at a Fe(110) surface has been studied as a function of translational energyET, internal energyEi, incident angleθi, and surface temperatureTs. Adsorption is activated, the sticking probability increasing steadily with translational energy with no evidence of a threshold for dissociation. Within experimental error there is no isotope effect or surface temperature dependence(180 K

Date: 1994
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DOI: 10.1142/S0218625X94000965

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