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MULTIPLE-SCATTERING APPROACH TO SURFACE EXAFS: THEORY VERSUS EXPERIMENT

J.J. Rehr
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J.J. Rehr: Department of Physics, FM-15, University of Washington, Seattle, WA 98195, USA

Surface Review and Letters (SRL), 1995, vol. 02, issue 01, 63-69

Abstract: Recent advances in polarized, high-order multiple-scattering calculations of extended X-ray absorption find structure (EXAFS) in surface systems are reviewed. Our method is based on curved-wave multiple-scattering (MS) theory and a scattering matrix formalism, which provides an efficient, unified treatment of XAFS, encompassing both EXAFS and X-ray absorption near-edge structure (XANES). Combined with multipath fits inr-space, such calculations have the potential to extend the capability of surface EXAFS experiments, going well beyond the first near-neighbor. The theory is illustrated with theoretical simulations. Our approach also gives a MS interpretation of continuum σ* shape-resonances.

Date: 1995
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DOI: 10.1142/S0218625X95000066

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