ALKALI-METAL ADSORPTION GEOMETRIES ON METAL SURFACES FROM PHOTOELECTRON-DIFFRACTION EXPERIMENTS

R. Fasel and J. Osterwalder
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R. Fasel: Institut de Physique, Université de Fribourg, 1700 Fribourg, Switzerland
J. Osterwalder: Physik-Institut, Universität Zürich-Irchel, Winterthurerstr. 190, CH-8057 Zürich, Switzerland

Surface Review and Letters (SRL), 1995, vol. 02, issue 03, 359-386

Abstract: The results of recent photoelectron-diffraction investigations of structures formed upon alkali-metal adsorption on metal surfaces are presented. A variety of unexpected phenomena that are in contrast to earlier beliefs is found to occur for many systems. Photoelectron diffraction, in its angle-scanned or energy-scanned mode, is found to provide a powerful and direct tool for the identification and investigation of unanticipated adsorbate geometries such as ontop adsorption, substitutional adsorption, and surface alloy formation.

Date: 1995
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DOI: 10.1142/S0218625X95000352

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