XPS STUDIES FOR AN IRON-ZIRCONIUM INTERFACE IN AN OXIDIZING ENVIRONMENT

Y.S. Li, W. Liu, P.C. Wong and K.A.R. Mitchell
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Y.S. Li: Department of Chemistry, University of British Columbia, 2036 Main Mall, Vancouver, British Columbia, Canada V6T 1Z1, Canada
W. Liu: Department of Chemistry, University of British Columbia, 2036 Main Mall, Vancouver, British Columbia, Canada V6T 1Z1, Canada
P.C. Wong: Department of Chemistry, University of British Columbia, 2036 Main Mall, Vancouver, British Columbia, Canada V6T 1Z1, Canada
K.A.R. Mitchell: Department of Chemistry, University of British Columbia, 2036 Main Mall, Vancouver, British Columbia, Canada V6T 1Z1, Canada

Surface Review and Letters (SRL), 1995, vol. 02, issue 06, 759-763

Abstract: A bimetallic film of iron and zirconium (thicknesses about 17 and 52 Å respectively) was deposited on a gold substrate and studied by XPS after exposing toO2(approximately103L) at room temperature, and then heating at progressively higher temperatures up to 400°C. An iron-oxide/iron/zirconiumoxide sandwich structure is present after the room-temperature exposure toO2, and this work shows the ready transfer ofOfrom the iron side to the zirconium side of theFe/Zrinterface.Femigration also occurs at 220°C and above, while by 300°C this diffusion appears to cause a substantial restructuring of theZrO2layer.

Date: 1995
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DOI: 10.1142/S0218625X95000686

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