PHOSPHORUS-CLUSTER CATIONS PRODUCED BY LASER ABLATION OF RED PHOSPHORUS

Rongbin Huang, Hongdi Li, Zhenyang Lin and Shihe Yang
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Rongbin Huang: Department of Chemistry, Hong Kong University of Science & Technology, Clear Water Bay, Kowloon, Hong Kong, P. R. China
Hongdi Li: Department of Chemistry, Hong Kong University of Science & Technology, Clear Water Bay, Kowloon, Hong Kong, P. R. China
Zhenyang Lin: Department of Chemistry, Hong Kong University of Science & Technology, Clear Water Bay, Kowloon, Hong Kong, P. R. China
Shihe Yang: Department of Chemistry, Hong Kong University of Science & Technology, Clear Water Bay, Kowloon, Hong Kong, P. R. China

Surface Review and Letters (SRL), 1996, vol. 03, issue 01, 167-169

Abstract: We report the generation of phosphorus-cluster cations containing up to 35 atoms by direct laser ablation of red phosphorus for the first time without supersonic expansion. Bare-cluster cations with an odd nymber of phosphorus atoms are preferentially produced. For even-number phosphorus atom clusters, the cluster cations with an odd number of hydrogens (present in trace amount in the source) are easily produced.

Date: 1996
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DOI: 10.1142/S0218625X96000334

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