PHOTOIONIZATION AND ELECTRONIC STRUCTURE OF HYDROGENATED LITHIUM CLUSTERS

B. Vezin, Ph. Dugourd, D. Rayane and M. Broyer
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B. Vezin: Laboratoire de Spectrométrie Ionique et Moléculaire (URA No. 171), CNRS et Université Lyon I, Bâtiment 205, 43 Boulevard du 11 Novembre 1918, 69622 Villeurbanne Cedex, France
Ph. Dugourd: Laboratoire de Spectrométrie Ionique et Moléculaire (URA No. 171), CNRS et Université Lyon I, Bâtiment 205, 43 Boulevard du 11 Novembre 1918, 69622 Villeurbanne Cedex, France
D. Rayane: Laboratoire de Spectrométrie Ionique et Moléculaire (URA No. 171), CNRS et Université Lyon I, Bâtiment 205, 43 Boulevard du 11 Novembre 1918, 69622 Villeurbanne Cedex, France
M. Broyer: Laboratoire de Spectrométrie Ionique et Moléculaire (URA No. 171), CNRS et Université Lyon I, Bâtiment 205, 43 Boulevard du 11 Novembre 1918, 69622 Villeurbanne Cedex, France

Surface Review and Letters (SRL), 1996, vol. 03, issue 01, 171-175

Abstract: The ionization-potential measurements ofLinHmclusters with3≤n≤11and0≤m≤6are presented. Their evolution is dominated by the number of electrons which are delocalized in the cluster. The analysis is in favor of a segregation between a metallic part and an insulating part in the mixed cluster. By comparison with alkali-halide clusters results, the existence of possible cuboid structures is discussed.

Date: 1996
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DOI: 10.1142/S0218625X96000346

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