STRUCTURES OF ORGANOMETALLIC CLUSTERS: Vn(BENZENE)mANDCon(BENZENE)m

K. Hoshino, T. Kurikawa, H. Takeda, A. Nakajima and K. Kaya
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K. Hoshino: Department of Chemistry, Faculty of Science and Technology, Keio University, 3–14–1 Hiyoshi, Kohoku-ku, Yokohama-223, Japan
T. Kurikawa: Department of Chemistry, Faculty of Science and Technology, Keio University, 3–14–1 Hiyoshi, Kohoku-ku, Yokohama-223, Japan
H. Takeda: Department of Chemistry, Faculty of Science and Technology, Keio University, 3–14–1 Hiyoshi, Kohoku-ku, Yokohama-223, Japan
A. Nakajima: Department of Chemistry, Faculty of Science and Technology, Keio University, 3–14–1 Hiyoshi, Kohoku-ku, Yokohama-223, Japan
K. Kaya: Department of Chemistry, Faculty of Science and Technology, Keio University, 3–14–1 Hiyoshi, Kohoku-ku, Yokohama-223, Japan

Surface Review and Letters (SRL), 1996, vol. 03, issue 01, 183-185

Abstract: Metal-molecule clusters,Vn(benzene)m,Con(benzene)m, and their ions, were synthesized by the reaction of laser-vaporized vanadium atoms with benzene vapor. Both neutral and cationicVn(benzene)mclusters exhibit magic number behavior atm = n + 1(n = 1–5), which was explicable in terms of multiple-decker sandwich structure.

Date: 1996
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DOI: 10.1142/S0218625X9600036X

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