SIZE EFFECTS AND THE ROLE OF NONADDITIVE FORCES IN NEUTRAL AND ANIONIC SILVER-CLUSTER STABILITY

I.G. Kaplan, R. Santamaría and O. Novaro
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I.G. Kaplan: Instituto de Física, Universidad Nacional Autónoma de México, Apartado Postal 20–364, 01000 México, D.F., México
R. Santamaría: Instituto de Física, Universidad Nacional Autónoma de México, Apartado Postal 20–364, 01000 México, D.F., México
O. Novaro: Instituto de Física, Universidad Nacional Autónoma de México, Apartado Postal 20–364, 01000 México, D.F., México

Surface Review and Letters (SRL), 1996, vol. 03, issue 01, 235-239

Abstract: The precise quantum-chemical study of neutral and anionic silver clusters manifests the pronounced size effect for the vertical ionization potential (VIP), vertical detachment energy (VDE), and atomic detachment energy(ε1). The additive and nonadditive contributions to the binding energy of clusters are calculated and their role in the cluster stability is discussed.

Date: 1996
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DOI: 10.1142/S0218625X96000462

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