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STATIC POLARIZABILITIES OF CHARGED SILVER METAL CLUSTERS EXTRACTED FROM THE OPTICAL SPECTRA

Josef Tiggesbäumker, Lars Köller and Karl-Heinz Meiwes-Broer
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Josef Tiggesbäumker: Fachbereich Physik, Universität Rostock, Universitätsplatz 3, 18055 Rostock, Germany
Lars Köller: Fachbereich Physik, Universität Rostock, Universitätsplatz 3, 18055 Rostock, Germany
Karl-Heinz Meiwes-Broer: Fachbereich Physik, Universität Rostock, Universitätsplatz 3, 18055 Rostock, Germany

Surface Review and Letters (SRL), 1996, vol. 03, issue 01, 509-513

Abstract: The use of sum rules appears to be a powerful tool for obtaining experimental data on static properties of charged metal clusters which are currently not available. For this purpose the optical spectra of the clusters must be known. The measured absorption profiles of sputtered, i.e. hot,$Ag_N^+$and$Ag_N^-$which have been measured in our group give information about the desired properties. The extracted static polarizabilities show a distinct shell structure which reflects the overall electronic shape of the cluster. A comparison is made withAgNand positive alkali metal clusters. The polarizabilities of closed-shell$Ag_N^+$and$Ag_N^-$are in reasonable agreement with SIC-LDA corrected RPA polarizabilities.

Date: 1996
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DOI: 10.1142/S0218625X96000929

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