REACTIONS OF MONOVALENT METAL IONS(M+)WITH MIXED MOLECULAR CLUSTERS(NH3)m(H2O)nAS STUDIED BY LASER-ABLATION MOLECULAR BEAM (LAMB) METHOD: PREFERRED OR NONSPECIFIC COORDINATION

H. Sato, A. Matsuzaki, S. Nishio, Y. Horiki and O. Ito
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H. Sato: Department of Chemistry for Materials, Faculty of Engineering, Mi’e University, Tsu 514, Japan;
A. Matsuzaki: Department of Chemistry for Materials, Faculty of Engineering, Mi’e University, Tsu 514, Japan
S. Nishio: Department of Chemistry for Materials, Faculty of Engineering, Mi’e University, Tsu 514, Japan
Y. Horiki: Department of Chemistry for Materials, Faculty of Engineering, Mi’e University, Tsu 514, Japan
O. Ito: Department of Chemistry for Materials, Faculty of Engineering, Mi’e University, Tsu 514, Japan

Surface Review and Letters (SRL), 1996, vol. 03, issue 01, 671-674

Abstract: Three distinct types of competitive solvation around monopositive metal ions in the gas phase have been revealed by the laser-ablation molecular beam method using binary clusters in the molecular beam: (i) preferred solvation of one of the two components, (ii) essentially nonselective solvation, and (iii) magic-number-like behavior of one component in the presence of the other component in the outer solvation sphere.

Date: 1996
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DOI: 10.1142/S0218625X96001200

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