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PHOTODISSOCIATION OF${\rm{C}}_n^+$CLUSTERS

R. Bouyer, P. Monchicourt, M. Perdrix, P. Pradel and F. Roussel
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R. Bouyer: CEA Saclay, DRECAM/SPAM, 91191 Gif sur Yvette, Cedex, France
P. Monchicourt: CEA Saclay, DRECAM/SPAM, 91191 Gif sur Yvette, Cedex, France
M. Perdrix: CEA Saclay, DRECAM/SPAM, 91191 Gif sur Yvette, Cedex, France
P. Pradel: CEA Saclay, DRECAM/SPAM, 91191 Gif sur Yvette, Cedex, France
F. Roussel: CEA Saclay, DRECAM/SPAM, 91191 Gif sur Yvette, Cedex, France

Surface Review and Letters (SRL), 1996, vol. 03, issue 01, 789-791

Abstract: Photodissociation of jet-cooled, mass-selected${\rm{C}}_n^-$clusters with16≤n≤36has been analyzed as a function of the dissociation laser fluence. From the dependence of the${\rm{C}}_n^+$depletion, the number of absorbed photons and the absorption cross section have been determined. The dissociation energy is deduced from the internal energy before fragmentation. A decreasing stability is observed from${\rm{C}}_{16}^+$to${\rm{C}}_{29}^+$. Above${\rm{C}}_{30}^+$, two isomeric forms are found, with one having a higher stability.

Date: 1996
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DOI: 10.1142/S0218625X9600142X

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