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SYNTHESIZED “IN SITU” IN REVERSE MICELLES OF SILVER-SULFIDE SEMICONDUCTORS

M.P. Pileni, L. Motte, F. Billoudet and C. Petit
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M.P. Pileni: Université P. et M. Curie, Laboratoire SRSI, BP 52, Bat 74, 4 place Jussieu, 75005 Paris, France;
L. Motte: Université P. et M. Curie, Laboratoire SRSI, BP 52, Bat 74, 4 place Jussieu, 75005 Paris, France;
F. Billoudet: Université P. et M. Curie, Laboratoire SRSI, BP 52, Bat 74, 4 place Jussieu, 75005 Paris, France
C. Petit: Université P. et M. Curie, Laboratoire SRSI, BP 52, Bat 74, 4 place Jussieu, 75005 Paris, France;

Surface Review and Letters (SRL), 1996, vol. 03, issue 01, 1215-1218

Abstract: Functionalized reverse micelles are used to control the size of silver sulfide,Ag2S, nanosize particles. The size of the crystallites varies linearly with the water content from 2 to 10 nm. The particles have been coated with dodecanethiol and extracted from micelles. The size of the particles dispersed in heptane has been determined by small-angles x-ray scattering (SAXS) experiments and compared to those obtained by transmission electron microscopy (TEM). A good agreement between results is obtained by these two techniques. A drop of particles previously dispersed in heptane is dried on a carbon grill. A network of the particles forming monolayers of crystallites in a hexagonal distribution appears.

Date: 1996
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DOI: 10.1142/S0218625X96002199

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